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Metallica
Tone profile
What makes this tone
Signal chain
Tone Character
Recorded tone character
Gain character
Raw, high-gain boosted-Marshall thrash distortion with a sharp attack.
Bass
Fuller than Kill 'Em All but still controlled for speed.
Mids
Moderately scooped, not yet the extreme Justice-era carve.
Treble
Bright and cutting.
Brightness / presence
Forward and energetic.
Compression
Tight but still more open/raw than later Mesa-driven records.
Effects
Ride-era Marshalls with overdrive/distortion boost; Hammett specifically documents a Tube Screamer and wah for lead work.
Evidence / Sources
Tone character: raw, aggressive, bright, tight, crunchy, fast, cutting, dry
This seed represents the main rhythm character. Hammett's Tube Screamer/wah evidence is lead-specific, while Hetfield had moved to the Explorer shape by the album.
Ride-era Marshalls with overdrive/distortion boost; Hammett specifically documents a Tube Screamer and wah for lead work.
Guitar
Gibson Explorer as Hetfield's main Ride the Lightning-era rhythm reference
Kirk Hammett used a Flying V for lead work
Amp
100W Marshall/JCM800-era studio architecture
lead work used Tube Screamer boost, and the band relied on a particularly good Marshall sourced in Denmark after their own amps were stolen
Channel
Likely high-gain Marshall
Pickup
Likely bridge humbucker