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Metallica
Tone profile
What makes this tone
Signal chain
Tone Character
Recorded tone character
Gain character
Raw early-thrash distortion with less compression and polish than later Metallica tones.
Bass
Moderate and fairly loose by later Metallica standards.
Mids
Noticeably present; the Kill 'Em All sound is not the deep Mesa scoop of later records.
Treble
Bright and abrasive for pick definition.
Brightness / presence
Open and cutting.
Compression
Moderate, with a rougher and more dynamic edge.
Effects
Kill 'Em All rhythm tone is associated with a hot-rodded Marshall and distortion/boost pedal; lead boost choices differ between Hetfield and Hammett.
Evidence / Sources
Tone character: raw, crunchy, aggressive, mid-forward, fast attack, dry, abrasive, early-thrash
The exact title-track knob positions are not documented. This is an early-thrash reference: more midrange and rawness than the later Mesa/Boogie-era Metallica sound.
Kill 'Em All rhythm tone is associated with a hot-rodded Marshall and distortion/boost pedal; lead boost choices differ between Hetfield and Hammett.
Guitar
Electra 2236 Flying Wedge / white Flying V-style guitar as Hetfield's early rhythm reference
Amp
Hot-rodded Marshall Super Lead/100W Marshall-family setup with pedal drive for the Kill 'Em All-era rhythm sound
Channel
Likely high-gain Marshall input
Pickup
Likely bridge humbucker